A very low ppb of DO can cause severe corrosion by pitting. Some power plants are successfully operating carbon steel boiler systems with demineralized water. Though provision has been kept to dose ammonia at deaerator outlet and boiler fill It should be between 1 and 2 ppm total ammonia, which is ammonia plus ammonium (NH3 and NH4+). To correct the pH chemicals like ammonia, mophylene or Cyclohexylamine are used. (III) Anhydrous ammonia feeding facilities shall be located in a separate enclosed room that meets all of the requirements of subparagraph (5) (E)1.A. An investigation has been made into the accuracy of ammonium-selective (ammonium-responsive) glass electrodes for determining ammonia (10 to 1000 g 1 1) in boiler feed-water and similar high-purity water samples from power stations.The electrode potential follows the Nernst equation in samples containing up to 10 000 mg 1 1 of ammonia, the pH of which is Proper treatment of boiler feedwater effectively protects against corrosion of feedwater heaters, economizers, and deaerators. Typically, the most effective dosage of hydrazine is 3:1 parts hydrazine to the expected level of dissolved oxygen. Mostly there are two chemicals will be added in boiler feed water for de-aeration. To correct the pH chemicals like ammonia, mophylene or Cyclohexylamine are used. 1,975. Review score. Courtesy: M&M Engineering Associates Inc. Gradually, as aging feedwater heaters are replaced, plants often choose to go with a stainless steel alloy such as 304 or 316 for feedwater tubing. 3.1 Ammonia Dosing Skid Ammonia dosing skid is common for both HRSG and it is Boiler Water Treatment. Ammonia dosing is recommended for most HRSGs to maintain pH 25C within a range of 9.610.0. The secret is the water must be oxygen free. They are hydrazine & ammonium hydroxide. Hydrazine for oxygen scavenging from the boiler. But the boiler feed water requirement is 8.5 to 9.2 pH. To correct the pH chemicals like ammonia, mophylene or Cyclohexylamine are used. All these chemicals are volatile and depending on Liquid-Vapour ratio will get evaporated in the drum resulting to reduction in pH of the drum. Two chemicals for the same purpose. Why morpholine dosing better than ammonia dosing in boiler feed water? The purpose of ammonia dosing is to control the pH of water; pH is kept slightly alkaline to avoid corrosions from chloride and other salts, whereas DO is scavenged by dosing hydrazine. Use of polymers further aids in conditioning any suspended solid contamination that may have entered with the boiler feed water. Supplied as a 35% solution. It is dosed for chemical de-aeration. Because of this we try to operate the boiler at the lowest possible corrosivity relative to pH (Note: this is only for boiler operating without high purity feedwater). NH3 dosing is carried out in feed water side i.e. 4Fe + 6H 2 O + 3O 2 4Fe (OH) 3 (1) That However, only explosion- proof, electric xtures shall be used in the room. As for the internal treatment of boiler water, this process requires conditioning of impurities in the water, which means that the water is softened with softening chemicals such as sodium phosphate and soda ash. Oxygen Scavengers - Most common type is 38%, pH < 4. But the boiler feed water requirement is 8.5 to 9.2 pH. TSP dosing is carried mostly in Drum. 3.3.4 Rusty water in the boiler gage glass is a sure sign of acid corrosion in the boiler feedwater/condesate system or in the boiler itself. step. water steam cycle (gas project) l.p. dosing d.m. As for the internal treatment of boiler water, this process requires conditioning of impurities in the water, which means that the water is softened with softening chemicals such as sodium phosphate and soda ash. Acidic compounds (CO2, DW leaks, etc) need to be neutralized. A boiler product contains 10% EDTA and 15% polymer. Ammonia Dosing Device Applications. N 2 H 4. Ideally the feed water should be in the range of pH 8.5 9.5. of this rule for chlorine gas feeding facilities. Ammonia is toxic only to animals that breathe oxygen. The other day here we cycled a reef tank and tested it for completion by just adding water, rocks and sixty days wait. The safe pH range for steam boilers is between 8.5pH & 12.7pH, whilst the recommended level is between 10.5pH & 12.0pH. LP DOSING AND OXYGENATED TREATMENT SYSTEM AT SIPAT AMMONIA DOSING Cycle pH is controlled by feeding an ammonia from a pump having a automatic stroke adjustment. Reaction score. VOL. The pH of demineralized water is normally a pH of 10 since the efflluent is in the form of sodium hydroxide. 11/26/2010 1:50 AM. 12] TREATMENT OF FEED AND BOILER WATER 2009 recorded under the symbol Z. Fig. Product name: Dosing device Bracket: SUS304/316. We only dose phosphate to our MP drum. Medium or high pressure boiler condensation water, feed water treatment.Quick Details. en Change Language. +0 / 0 / -0. Because the condenser and feedwater heaters often contain copper alloys, ammonia levels must be carefully controlled, lest excessive amounts increase copper corrosion. of this rule for chlorine gas feeding facilities. It may be good for Cu alloy but In low-flow areas of the condensate system, Fe(OH) 2 Register to Reply. If copper fed lines or heaters are used, restrict the feed water pH to For reclamation drain from makeup water desalination systems and condensate desalination systems, and equipment washing If NH3 goes into drum 70% of NH3 gets evaporated and escape with the steam Inferred pH in Steam Plant Water Chemistry Monitoring - Emersonwith small amounts of chemicals for the purpose of reducing corrosion. Total product dose is based on the sum of that required to react with the dissolved oxygen plus that required to establish a residual in the feedwater. +0 / 0 / -0. They include: Ammonia for dosing in the boiler steam-water cycle system to control the pH. One chemical group for boilers is for steam boilers and the second is for hot water boilers. CHEMICAL INJECTION INTERNAL TREATMENT Ammonia juga dapat berfungsi sebagai penetralisir asam lemah yang terjadi akibat adanya gas CO2 yang merupakan salah satu komponen penyebab korosi. Small reductions in boiler or condenser If the hardness goes up to Measure Ammonia. water rft condenser d/a This surging sound is distinctive. In order to control the same, continuous dosing of dilute solution of Ammonia is done at CEP discharge after CPU. zzz 3'+fhqwhu frp 3'+ &rxuvh 0 zzz 3'+rqolqh ruj 3djh ri ,q d khdy\ xvh lqgxvwuldo vwhdp erlohu wkh zdwhu frxog eh frpsohwho\ uhsodfhg dv riwhq dv rqfh hdfk krxu Accepta 2061 is compatible with most other internal boiler treatment programmes. Thus an increase in feedwater pressure at the boiler inlet (i.e., the increase in feed-water pump power) has been curbed. A very low ppb of DO can cause severe corrosion by pitting. The purpose of ammonia dosing is to control the pH of water; pH is kept slightly alkaline to avoid corrosions from chloride and other salts, whereas DO is scavenged by dosing hydrazine. Nobody in the history of reefing has ever starved a set in cycle, its purely a forum circulated notion. Ammonia is a compound of nitrogen and hydrogen with the formula NH 3.A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Browse SUEZs Boiler Water Treatment Chemicals. Scribd is the world's largest social reading and publishing site. Introduction to Marine Boiler Water Dosing. For feedwater dosing, a target pH of 9.4-9.6 should be set (with either ammonia or proprietary amine dosing). When added to condensate and feedwater, ammonia elevates the pH and reduces waterside and steamside corrosion of ferrous metals. Feed Accepta 2061 to the storage section of the de-aerator below the water line via an injector. Add to basket. Oxygen is generally measured before de-aerator and maintained below 20 ppb to minimize pre-boiler corrosion. A very low ppb of DO can cause severe corrosion by pitting. Feedwater dosage is 8.8 ppm to yield 10 ppm free EDTA and 26 ppm polymer. To ensure a proper pH at operating Temp in boiler water and boiler feed water, a measured pH above 9.4 and 9.2 respectively is recomended. 2.Scale and deposit formation on heat transfer surfaces. Boiler feed water/Condensate water should have proper pH (8-8.5) in order to protect the system from corrosion. 1,975. Review score. Boiler Water Treatment Services; Boiler Water Treatment Chemicals; Dosing Equipment; Water Treatment Plant and Equipment; Chlorine Dioxide. DM water can best be produced in the range of 6.8 to 7.2 pH. 4Fe + 6H 2 O + 3O 2 4Fe (OH) 3 (1) Small reductions in boiler or condenser Coagulant ad flocculant The fate of the ferrous ion (Fe2+) depends on condensate temperature, pH, and flow conditions. The main purpose of internal treatment is to properly reduce hardness, sludge and remove oxygen from the feed water. Prepare water and adjust salinity, and temperature. Horizontal vessel also has a sparger system which keep boiler feed water warm. Inherent alkalinity helps maintain feed water alkalinity within parameters of 8.6 to 9.0. The purpose of ammonia dosing is to control the pH of water; pH is kept slightly alkaline to avoid corrosions from chloride and other salts, whereas DO is scavenged by dosing hydrazine. FEED WATER RECIRCULATION VIA BOILER TO ACHIEVE FEED WATER QUALITY. Air yang akan dibuat menjadi steam di dalam boiler merupakan hasil CO2 + H2O H2CO3 kondensasi uap ditambah dengan make up water. There are two main groups of Chemicals for Boilers to choose from. pre-boiler side (before Eco inlet). All these chemicals are volatile and depending on Liquid-Vapour ratio will get evaporated in the drum resulting to reduction in pH of the drum. They typically dose ammonia to do a fishless cycle. A key issue with high conductivity in boiler water is that operational issues such as scaling can occur, which is a buildup of solid material in the boiler. Translate PDF. Morpholine, which is an organic amine, is sometimes used in place of ammonia. Another common volatile treatment chemical is hydrazine, which is a chemical oxygen scavenger. Solid treatment chemicals are fed only to boiler water, never to condensate and feedwater. All these chemicals are volatile and depending on Liquid-Vapour ratio will get evaporated in the drum resulting to reduction in pH of the drum. Reaction score. chemical dosage. The chemical dosing system comprises a feed water ammonia-adding sub system and a boiler water dosing sub system, wherein the feed water ammonia-adding sub system comprises a first liquor tank, a first liquor tank stirring device and an ammonia adding unit; a liquor outlet of the first liquor the feed water pump internals. Typical damage to any carbon-steel materials, including piping, boiler tubes and drums, will include pitting and thinning of the components due to the oxygen attacking the iron in the carbon steel (Figure 1). Boiler Feedwater Treatment Chemical Injection (or Chemical Dosing) For safe and efficient operation, the quality of feedwater, steam, and condensate in boiler plants must be controlled and maintained in the most favorable conditions. added to condensate and feedwater, ammonia elevates the pH and reduces are An investigation has been made into the accuracy of ammonium-selective (ammonium-responsive) glass electrodes for determining ammonia (10 to 1000 g 1 1) in boiler feed-water and similar high-purity water samples from power stations. chemical dosage. Dosing System basics In a typical boiler feed water dosing system: The HP Dosing system doses direct into boiler drum, under high pressure. Steam generation in the ammonia industry is not a simple task, as water purity is of critical importance to heat transfer performance, process efficiency and controlling total cost of ownership. As a knock on effect will slightly increase boiler water alkalinity. Stable at high temperatures so is used more than hydrazine to control the steam line alkalinity as there is less chance of copper corrosion which occurs with the prescience of ammonia Proper boiler water treatment eliminates sludge and scale deposits within the boiler. Wiki User 2013-08-05 09:44:02 Corals, which incorporate xooanthalae algae as a symbiotic dont breath oxygen, and algae is known to use ammonia as fuel. Abstract. Fineamin products have a very low degradation ratio, 1 ppb for 1 ppm injected product. The first priority is to minimize the amount of make-up water. Regular testing of a ships boiler feed water should be carried out to determine the extent of chemical dosing required to maintain the boilers efficiency in supplying high pressure superheated steam to the main and auxiliary steam turbines. During normal operation, Deaerator effluent was found free of carbon dioxide with oxygen content in the range of 5 - 10 ppb. AVT programs (volatile amine, such as ammonia dosing) were introduced to overcome the problems associated with the phosphate corrosion in high pressure boilers. Dosing depends on bicarbonate alkalinity in BFW and the stability of amine bicarbonate according to Betz; but nowadays these can be practically 0, since there are no A 1:1 neutralizing amine blend of CHA and morpholine was also injected at a very low rate into the high-pressure boiler feedwater. During this same period there were essentially no changes to the HP or IP boiler water treatment programs, and the hydroquinone feed was continued for oxygen scavenging and passivation. close menu ammonia dosing purpose in boiler feed water, The former part of ZOZEN SZL coal fired boiler body is surrounded by membrane wall, its upper part connects with boiler drum and lower part connects with header, which forms a combustion chamber to absorb the radiated heat from furnace there are dense convection tube bundles between the back side of upper and lower Answer (1 of 2): Chemical reactions happen very fast at elevated temperatures. This pitting is a result of the basic reaction for the formation of rust (Equations (1) and (2)). from boiler water in high pressure boilers. Additions of hydrazine to the feed water into the feed system must be continuous and sufficient quantity to remove the last traces of oxygen from the feed water and to leave a small excess. Ammonia is commonly used cheaper material to maintain pH in boiler water. Volatile chemicals evaporate from the water into the steam in a gaseous form. dosing hydrazine dosing bfp ammonia dosing cep. They do not form a solid phase and thus they do not form a scale or deposit on heat transfer surfaces. For boiler water treatment applications, the metering pumps used must be able to dispense accurate chemical dosages every time in order to ensure the proper chemical treatment of the boiler feed water. Feedwater Boiler water pH of feedwater Ammonia Hydrazine Disodium phosphate Feed water: AVT (R) Boiler water: PT Used Used Used 8.5 to 9.7 Feed water/Boiler water: High-AVT (LO) Used Not used Need not be used 9.8 to 10.3 * In cases where PT is replaced with High-AVT, it is recommended that chemical cleaning should be performed They typically dose ammonia to do a fishless cycle. The purpose of ammonia dosing is to control the pH of water; pH is kept slightly alkaline to avoid corrosions from chloride and other salts, whereas DO is scavenged by dosing hydrazine. Therefore a slight residual of hydrazine is kept in the system. dear, both morpholine and hydrazine or ammonia are used in conjunction. Chemical dosages are based on the amount and type of impurities in the feedwater. Boiler feed water (BFW) preheater in ammonia production Boiler feed water (BFW) preheater in ammonia production TECHNICAL DATA Gas side mass flow 161,500 kg/h Water side mass flow 303,000 kg/h Heat duty 22.8 MW Design pressure gas side 35.4 barg Design pressure water side 131 barg SCOPE OF SUPPLY BFW preheater nature provided the free bacteria and their feed. where Ammonia used for boosting PH in condensate (feed water). feed water has to alkalized to PH of 9 or little high (high alkalized solution causes caustic corrosion), to reduce oxidation and to support the formation of a stable layer of Magnetite on water side surface of boiler, protecting metal from further corrosion. The alkalinity and phosphate values, in terms of sodium hydroxide, sodium carbonate, total alkalinity as equivalent sodium carbonate, and sodium phosphate are then calcu-lated in accordance with table 2. When this occurs, the boiler becomes less efficient and increases the fuel consumption of the unit. None is needed. Place of Origin: Zhejiang, China Brand Name:Dongkai. Close suggestions Search Search. The electrode potential follows the Nernst equation in samples containing up to 10 000 mg 1 1 of ammonia, the pH of which is (III) Anhydrous ammonia feeding facilities shall be located in a separate enclosed room that meets all of the requirements of subparagraph (5) (E)1.A. Boiler Water Pretreatment Purpose - Statistically 75% of all boiler water problems manifested in the boiler have a root cause in the pretreatment system Process - Walk through the processes, key factors, monitoring, and operational impacts of pretreatment systems Payoff - Cleaner boilers, increased energy Heloo friends in this video we explain why we dosing ammonia & hydrazine in boiler feed water also explain where lp dosing given in feed water system. The chemical dosing system comprises a feed water ammonia-adding sub system and a boiler water dosing sub system, wherein the feed water ammonia-adding sub system comprises a first liquor tank, a first liquor tank stirring device and an ammonia adding unit; a liquor outlet of the first liquor The feedwater must be specially treated to avoid problems in the boiler and downstream systems. The Feed Water pump is designed to pump liquids, not steam, so it cavitates. Ammonia is not toxic to coral. Boiler Dosing System Operation Procedure WCP-OP-005 Page 8 of 26 3.0 SYSTEM DESCRIPTION The purpose of the ammonia dosing unit is to control the pH of the boiler feed water by dosing NH 3, the two phosphate dosing units control the pH of the HP evaporator systems by dosing Na 3 PO 4. N 2 H 4 is used to scavenge Dissolved Oxygen and protect Copper alloys from Ammonia. Used in boiler operating above 32 bar, will not readily react with O 2 below 50 o C hence risk of copper corrosion occurs with the ammonia stripping off the continuously reforming copper oxides. pitting can result with possible rupture of boiler condensate piping or boiler tubes. When steam condenses, the chemicals dissolve into the water. The main purpose of internal treatment is to properly reduce hardness, sludge and remove oxygen from the feed water. Metering pumps are designed to pump into low or high discharge pressures at controlled flow rates. Ammonia and hydrazine are use in LP dosing.where it was dosed in low it may corrode system dearator has also same purpose to remove oxygen but it has. Two types of AVT are; i) AVT (R) Using Ammonia (NH3) and as reducing agent like Hydrazine (N 2 H 4), ii) AVT (O) same as AVT minus reducing agent i.e. Finally, treated deaerated boiler feed water sent to the boiler via boiler feed pump. 4.5.1 All-volatile treatment (AVT) AVT is defined as the exclusive use of volatile conditioning agents. Add full dose of QuikCycl at 4 drops per gallon or 1 ml per 5 gallons of tank capacity. However, only explosion- proof, electric xtures shall be used in the room. maintain feed water ph using ammonia turbine steam boiler t.s.p. To maintain boilers and turbines at a high level of availability and efficiency, the chemical control of water and steam purity is aimed at the prevention of: 1.Corrosion of feed, boiler and steam systems. It should be noted that the level of ammonia in the condensate and feed water should not exceed 0.5 ppm (as NH3) for a copper alloy pre-boiler system and 1.0 ppm (as NH3) for a Cu free pre-boiler system. Generally it is desirable to have a slightly high pH for boiler feed water. The excess will break down to ammonia in the boiler (equation 3-23) and may cause problems in copper condensate systems unless they are air free. (IV) Anhydrous ammonia contact with chlorine or uorine can create Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a 3.Deposition and corrosion of turbines. both morpholine and hydrazine or ammonia are used in conjunction. 3.3.5 Make-up water is the major source of carbon dioxide. 24, NO. Products: boiler feed water J5.0 Plunger Chemical Liquid Injection Pump specialty metering pump J5.0 series Plunger dosing pumps are primarily used in Chemical dosages are based on the amount and type of impurities in the feedwater. Steam stripped out the dissolved gases from boiler feed water & these gases are exit out via vents which is given at top of the horizontal vessel. Untreated boiler feed water can cause corrosion and fouling. Corals, which incorporate xooanthalae algae as a symbiotic dont breath oxygen, and algae is known to use ammonia as fuel. Why ammonia is dosed in boiler? The utility model relates to a chemical dosing system for feed water and boiler. The purpose of ammonia dosing is to control the pH of water; pH is kept slightly alkaline to avoid corrosions from chloride and other salts, whereas DO is scavenged by dosing hydrazine.